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Oral presentation

Extraction equilibrium and structural chemistry of rare earths with a nitriloacetic acid diamide-type ligand

Shimojo, Kojiro; Kobayashi, Toru; Yokoyama, Keiichi; Yaita, Tsuyoshi

no journal, , 

We have developed a novel nitriloacetic acid diamide-type ligand, and investigated the extraction behavior of rare-earth metal ions using the ligand. It was found that the ligand provides a remarkably high selectivity for scandium among rare-earth elements. In addition, we clarified crystal structure of the complexes by single-crystal X-ray diffraction. The clear differences in the chemical structures between scandium complexes and lanthanum complexes were demonstrated.

Oral presentation

Investigation of the inhibition effect by adding a ZMH seeding crystal under the existence of Te

Sue, Kasumi*; Hirasawa, Izumi*; Miyazaki, Yasunori; Takeuchi, Masayuki

no journal, , 

no abstracts in English

Oral presentation

Reaction conditions for purification in the thermochemical water-splitting iodine-sulfur process

Sugimoto, Chihiro; Tanaka, Nobuyuki; Noguchi, Hiroki; Kamiji, Yu; Myagmarjav, O.; Ono, Masato; Takegami, Hiroaki

no journal, , 

no abstracts in English

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