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Shimojo, Kojiro; Kobayashi, Toru; Yokoyama, Keiichi; Yaita, Tsuyoshi
no journal, ,
We have developed a novel nitriloacetic acid diamide-type ligand, and investigated the extraction behavior of rare-earth metal ions using the ligand. It was found that the ligand provides a remarkably high selectivity for scandium among rare-earth elements. In addition, we clarified crystal structure of the complexes by single-crystal X-ray diffraction. The clear differences in the chemical structures between scandium complexes and lanthanum complexes were demonstrated.
Sue, Kasumi*; Hirasawa, Izumi*; Miyazaki, Yasunori; Takeuchi, Masayuki
no journal, ,
no abstracts in English
Sugimoto, Chihiro; Tanaka, Nobuyuki; Noguchi, Hiroki; Kamiji, Yu; Myagmarjav, O.; Ono, Masato; Takegami, Hiroaki
no journal, ,
no abstracts in English